You can also try going to microsoft.com and download sysinternals suite.
http://technet.microsoft.com/en-us/sysinternals/bb842062.aspxIf you run diskext then it will give you a map. Also ntfsinfo provides good info.
But, whether hardware or software RAID, the problem is one of these:
1. You have a drive failure and the system is running in degraded mode (half of the RAID is offline), and surviving disk has unrecoverable read error. (Make sure hardware is OK and all 4 disks online and no errors in RAID event log)
2. The RAID is not degraded, and both disks happen to have an unrecoverable read error at same block (unlikely . data is bad at that block so you need to scan using some software to find out what file is involved -- more tricky but let's eliminate 1 & 3 first as they are more likely)
3. Filesystem corruption (run chkdsk /f) so that the filesystem thinks that a chunk of the file is on a block that doesn't exist, i.e, the next block number is higher than the highest possible block number for your available storage.