Essentially all domain authentication is done with kerberos. All non-domain authentication by default tries to use kerberos first if supported, if not, then it bumps down the chain to NTLMv2, then to NTLM ...
Here is a good link that gives an overview of the windows authentication methodologies.
http://technet.microsoft.com/en-us/library/cc755284%28WS.10%29.aspx