You will need to configure a shared namespace.
Also as they are in different orgs you will have to exmerge the mailboxes out of 2003 and then import them into 2010.
Brick level backup of 2003:
http://www.petri.co.il/brick_level_backup_of_mailboxes_by_using_exmerge.htmimport-mailbox:
http://technet.microsoft.com/en-us/library/bb629586.aspxshared namespace: